Spatial uniformity of the spectral radiance by white LED-based K2CaP2O7:Ce3+, Tb3+ phosphor

Ha Thanh Tung, My Hanh Nguyen Thi

Abstract


The K2CaP2O7:Ce3+, Tb3+ (Ce/Tb-KCPO) phosphor with blue-to-green emission is introduced in this study. The synthesis of the phosphor is carried out with the solid-state approach. The phosphor characteristics, including X-ray diffraction, luminescence lifespan, and thermal stability are measured and examined. The data show that Ce/Tb-KCPO phosphor displays a broadband emission from blue to green when excited by ultraviolet source. Besides, the ion Ce3+ strengthen the emission of Tb3+ ion through an efficient energy-transfer mechanism, which is estimated about 82.51%. The main electric interaction responsible for this Ce/Tb energy transfer is the dipole-quadrupole one. The phosphor also benefits the luminous intensity and color uniformity of the light-emitting diodes (LED) white-light output. Therefore, the Ce/Tb-KCPO phosphor can be a potential material for high-power white light-emitting diodes (WLED).

Keywords


K2CaP2O7:Ce3+, Tb3+; Light-emitting diodes devices; Luminescent; Phosphors; Spectrum

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DOI: https://doi.org/10.11591/eei.v12i5.5344

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Bulletin of Electrical Engineering and Informatics (BEEI)
ISSN: 2089-3191, e-ISSN: 2302-9285
This journal is published by the Institute of Advanced Engineering and Science (IAES) in collaboration with Intelektual Pustaka Media Utama (IPMU).